N-Heterocyclic Carbenes in Catalytic Organic Synthesis, Workbench Edition

$549.00
Publication Date:
Edition:
Pages:
Format:
ISBN:
August 2017
1
1072
Paperback/softback
9783132414303

These SOS volumes provide a user's guide to NHC chemistry and catalysis, thus facilitating the introduction of NHCs to novices and also helping to expand the repertoire of synthetic tools available to the more-advanced researcher, enabling the design of new catalysts and reactions.

Volume 1 provides a detailed introduction to NHCs, with discussion of their architectures and steric and electronic properties. The synthesis of NHC precursors, NHCs themselves, and metal-NHC complexes is described. The use of NHCs in cross-coupling chemistry (carbon-carbon and carbon-heteroatom bond formation), C-H bond functionalization, and addition reactions to carbon-carbon multiple bonds is reviewed.

Volume 2 covers the use of NHCs in the various types of metathesis reaction, polymerization, cyclization reactions, oxidation reactions, and carbonylation/carboxylation reactions. The use of NHCs in asymmetric transition-metal catalysis is highlighted, as are recyclable systems (biphasic, covalently immobilized, and ionically tagged systems), NHCs in flow chemistry, and recent advances in the use of NHCs in organocatalysis.

Category: Chemistry

These SOS volumes provide a user's guide to NHC chemistry and catalysis, thus facilitating the introduction of NHCs to novices and also helping to expand the repertoire of synthetic tools available to the more-advanced researcher, enabling the design of new catalysts and reactions.

These SOS volumes provide a user's guide to NHC chemistry and catalysis, thus facilitating the introduction of NHCs to novices and also helping to expand the repertoire of synthetic tools available to the more-advanced researcher, enabling the design of new catalysts and reactions.

Volume 1 provides a detailed introduction to NHCs, with discussion of their architectures and steric and electronic properties. The synthesis of NHC precursors, NHCs themselves, and metal-NHC complexes is described. The use of NHCs in cross-coupling chemistry (carbon-carbon and carbon-heteroatom bond formation), C-H bond functionalization, and addition reactions to carbon-carbon multiple bonds is reviewed.

Volume 2 covers the use of NHCs in the various types of metathesis reaction, polymerization, cyclization reactions, oxidation reactions, and carbonylation/carboxylation reactions. The use of NHCs in asymmetric transition-metal catalysis is highlighted, as are recyclable systems (biphasic, covalently immobilized, and ionically tagged systems), NHCs in flow chemistry, and recent advances in the use of NHCs in organocatalysis.

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